Journal
ACS CATALYSIS
Volume 3, Issue 2, Pages 192-195Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs300678n
Keywords
zeolites; alkylation; heterogeneous catalysis; nanomorphic; external surface
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Funding
- Research Center Program of IBS (Institute for Basic Science) in Korea [CA1201]
- Ministry of Science, ICT & Future Planning, Republic of Korea [IBS CA1301] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Nanomorphic *BEA, MTW, and *MRE zeolites were investigated as catalysts for isopropylation of benzene. From the deactivation pattern of the zeolites, we evaluated the contribution of external and internal active sites. These nanomorphic zeolites exhibited a high activity and long catalytic lifetime. Such catalytic properties can be explained by a large contribution of external sites, which have the advantage of slow deactivation.
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