Journal
ACS CATALYSIS
Volume 3, Issue 10, Pages 2190-2193Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs400533e
Keywords
palladium; N-heterocyclic carbenes (NHCs); arylation; sulfoxide; cross-coupling
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Funding
- EC
- Royal Society
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The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides in moderate to good yields (17 examples, 34-85%). Scope, limitations, and reaction mechanism are discussed.
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