Journal
ACS CATALYSIS
Volume 3, Issue 6, Pages 1365-1368Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs400250m
Keywords
alkene; dioxygenation; oxyamidation; metal-free; regioselective
Categories
Funding
- National Natural Science Foundation of China [21172106, 21074054]
- National Basic Research Program of China [2010CB923303]
- Research Fund for the Doctoral Program of Higher Education of China [20120091110010]
- MOE
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A new synthetic approach toward difunctionalization of alkenes has been developed under metal-free conditions. Various carboxylic acids and amines could react smoothly with alkenes to give dioxygenation and oxyamidation products, respectively. This organocatalytic process delivers 2-hydroxy alcohols directly from simple alkenes with high levels of region control.
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