4.8 Article

Migration of Cu Ions in SAPO-34 and Its Impact on Selective Catalytic Reduction of NOx NH3

Journal

ACS CATALYSIS
Volume 3, Issue 9, Pages 2158-2161

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cs400499p

Keywords

electron microscopy; heterogeneous catalysis; nitrogen oxides; selective catalytic reduction; zeolites

Funding

  1. Danish Ministry of Science, Innovation and Higher Education

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Migration of copper species from the surface region upon activation of Cu-SAPO-34 leads to a several-fold increase in catalytic activity for the selective catalytic reduction of NO with NH3. The temperatures required for the activation are higher than normal calcination temperatures and lead to a homogeneous transition metal distribution that renders Cu-SAPO-34 an industrially promising candidate for NO removal.

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