4.8 Article

Composition-Dependent Catalytic Activity of Bimetallic Nanocrystals: AgPd-Catalyzed Hydrodechlorination of 4-Chlorophenol

Journal

ACS CATALYSIS
Volume 3, Issue 7, Pages 1560-1563

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cs400282a

Keywords

Ag; Pd; nanocrystals; hydrodechlorination

Funding

  1. State Key Project of Fundamental Research for Nanoscience and Nanotechnology [2011CB932401, 2011CBA00500]
  2. National Key Basic Research Program of China [2012CB224802]
  3. National Natural Science Foundation of China [20921001, 21131004]

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Ag-Pd bimetallic nanocrystals (NCs) with tunable compositions and narrow size distributions were produced by a one pot synthesis. The NC growth process was investigated by time dependent TEM, XRD, and UV-vis studies. In the hydrodechlorination of 4-chlorophenol, the AgPdx (x = 2, 4, 6, 9, 19) showed pronounced composition-dependent catalytic activities, leading to the AgPd9 catalyst with excellent activity.:

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