Journal
ACS CATALYSIS
Volume 3, Issue 9, Pages 1951-1955Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs400409d
Keywords
cobalt Schiff base; phase transfer asymmetric catalysis
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Funding
- RFBR [13-03-92601-KO-a]
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Stereochemically inert and positively charged chiral complexes of Co-III prepared from Schiff bases derived from chiral diamines and salicylaldehydes were shown to be efficient catalysts of the asymmetric phase transfer benchmark reaction of alkylation of O'Donnell's substrate with alkyl halides. The enantiomeric purities of the reaction products were up to 92%.
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