Journal
ACS CATALYSIS
Volume 2, Issue 10, Pages 2082-2086Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs300413x
Keywords
heterogeneous catalysis; mesoporous materials; nanostructures; nitrides; selective oxidation
Categories
Funding
- L2H project of BMBF
- EnerChem project
- UNICAT project
- AvH Foundation
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Solvent-free oxidation of the primary C-H bonds in toluene to benzaldehyde has been achieved by using the metal-free catalyst g-C3N4 and O-2. It is the nanostructure of g-C3N4 that boosts the high selectivity by tuning the homogeneous oxidation to hetergeneous oxidation and capturing all free center dot O-2(-) radicals to effectively suppress the overoxidation of aldehydes.
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