4.8 Article

Electrocatalysts for Nonaqueous Lithium-Air Batteries: Status, Challenges, and Perspective

Journal

ACS CATALYSIS
Volume 2, Issue 5, Pages 844-857

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cs300036v

Keywords

lithium air battery; energy storage; electrocatalyst; oxygen reduction/evolution; lithium peroxide

Funding

  1. U.S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Materials Sciences and Engineering
  2. KC020105-FWP12152
  3. Pacific Northwest National Laboratory (PNNL)
  4. U.S. DOE
  5. Department of Energy [DE-AC05-76RL01830]

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The Li-air battery has recently emerged as a potentially transformational energy storage technology for both transportation and stationary energy storage applications because of its very high specific energy; however, its practical application is currently limited by the poor power capability (low current density), poor cyclability, and low energy efficiency. All of these are largely determined by interfacial reactions on oxygen electrocatalysts in the air electrode. In this article, we review the fundamental understanding of oxygen electrocatalysis in nonaqueous electrolytes and the status and challenges of oxygen electrocatalysts and provide a perspective on new electrocatalysts design and development.

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