Journal
ACS CATALYSIS
Volume 2, Issue 6, Pages 1221-1225Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs300214v
Keywords
dirhodium; asymmetric catalysis; cyclopropanation; halogen bond; mixed ligand; heteroleptic catalyst
Categories
Funding
- NSERC (Canada)
- Canada Research Chair Program
- Canadian Foundation for Innovation
- Centre in Green Chemistry and Catalysis (CGCC)
- Universite de Montreal
- NSERC (PGS D)
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A general method for the synthesis of chiral heteroleptic rhodium(II) tetracarboxylate catalysts is reported. The chlorinated TCPT unit was found to be an efficient polarity-control group, allowing the isolation of each complex from a mixture of six possible products. This approach contributes to enlarging the scope of accessible chiral Rh(II) catalysts and allowed further study of the halogen bond rigidification effect observed in chlorinated complexes.
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