Journal
ACS CATALYSIS
Volume 2, Issue 6, Pages 1042-1048Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs300090h
Keywords
Direct synthesis of hydrogen peroxide; Leach proof; Pd nanoparticles; Immobilization; on site production
Categories
Funding
- Ministry of Knowledge Economy (MKE) of Korea [10033093]
- National Research Foundation of Korea (NRF)
- Korea government (MEST) [2011-0017322]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10033093] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Ask authors/readers for more resources
The direct synthesis of hydrogen peroxide (DSHP) from H-2 and O-2 is conceptually the most ideal and straightforward reaction for producing H2O2 in industry. However, precisely tailored catalysts are still in progress for large scale production. Here, we report highly efficient and industrially relevant catalysts for the direct synthesis of H2O2 from H-2 and O-2 prepared by the immobilization of Pd nanocatalysts onto a functionalized resin. The continuous production of 8.9 wt % H2O2 and high productivity (180 g of H2O2 (g of Pd)(-1) h(-1)) is achieved under intrinsically safe and less-corrosive conditions without any loss of activity. We expect this approach is a substantial improvement of nanocatalysts for direct synthesis of hydrogen peroxide from hydrogen and oxygen and will greatly accelerate the industrially relevant process of on site production of hydrogen peroxide soon.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available