Journal
ACS CATALYSIS
Volume 1, Issue 10, Pages 1150-1153Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs200318n
Keywords
amine oxidation; photocatalyst; niobium oxide; selective oxidation; aerobic oxidation
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [17034036, 20037038, 19360365]
- Special Coordination Funds for Promoting Science and Technology (SCF)
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan
- JSPS
- Grants-in-Aid for Scientific Research [17034036, 20037038, 19360365] Funding Source: KAKEN
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Niobium oxide (Nb2O5) can function as a photocatalyst for selective oxidation of benzylamine rather than other semiconductor metal, oxides such as TiO2, ZnO, and WO3. Various amines including primary, secondary, and cyclic amines are also photo catalytically converted to corresponding imines in excellent yields by using Nb2O5 in an atmospheric pressure of O-2. Nb2O5 exhibits a catalytic activity with high selectivity even under visible light (lambda > 390 nm) irradiation, although Nb2O5 does not absorb visible light.
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