Journal
ACS CATALYSIS
Volume 1, Issue 11, Pages 1621-1630Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs200434s
Keywords
carbonylation; carbon monoxide; metal carbene; ketene; beta-lactam synthesis
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Funding
- Natural Science Foundation of China [20902005, 20832002, 210722009, 20821062]
- National Basic Research Program of China (973 Program) [2009CB825300]
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Carbonylation of metal carbene complexes, including the carbonylation of Group VI Fischer carbenes, is reviewed in this article. In particular, transition metal-catalyzed carbonylation of metal carbene complexes with carbon monoxide is discussed in detail. This type of carbonylation reactions provides an efficient access to ketene species, which are highly important in organic synthesis.
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