Journal
ACS CATALYSIS
Volume 1, Issue 8, Pages 917-922Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs200238v
Keywords
hydrodeoxygenation; HDO; furan; ruthenium; ruthenium phosphide
Categories
Funding
- National Science Foundation [CHE-0809433]
- DOE [DE-AC06-76RLO 1830]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0809433] Funding Source: National Science Foundation
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Ru2P/SiO2 and RuP/SiO2 catalysts were prepared by the temperature-programmed reduction (TPR) of uncalcined precursors containing hypophosphite ion (H2PO2-) as the phosphorus source. The Ru2P/SiO2 and RuP/SiO2 catalysts had small average particle sizes (similar to 4 nm) and high CO chemisorption capacities (90-110 mu mol/g). The Ru phosphide catalysts exhibited similar or higher furan (C4H4O) hydrodeoxygenation (HDO) activities than did a Ru/SiO2 catalyst, and the phosphide catalysts favored C-4 hydrocarbon products while the Ru metal catalyst produced primarily C-3 hydrocarbons.
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