Journal
ACS CATALYSIS
Volume 1, Issue 8, Pages 872-876Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs2002109
Keywords
metathesis; adsorption; trace impurities; ruthenium
Categories
Funding
- Heidelberg University
- state of Baden-Wurttemberg
- BASF SE
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We report on a series of six new pyridinealkoxide-bridged first and second generation ruthenium carbenes with similar or even higher activity in ring-opening metathesis polymerization (ROMP), cross metathesis (CM), and ring dosing metathesis (RCM) reactions than state-of-the-art catalysts. The new precatalysts show an extraordinarily high stickiness to commercially available silica, which significantly enhances their adsorptive separation from unprocessed reaction mixtures.
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