Journal
NATURE COMMUNICATIONS
Volume 5, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/ncomms6261
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Funding
- National Natural Science Foundation (NSFC) [21271163, U1232211]
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Theoretical and experimental results have revealed that the lithium-ion storage capacity for nitrogen-doped graphene largely depends on the nitrogen-doping level. However, most nitrogen-doped carbon materials used for lithium-ion batteries are reported to have a nitrogen content of approximately 10 wt% because a higher number of nitrogen atoms in the two-dimensional honeycomb lattice can result in structural instability. Here we report nitrogen-doped graphene particle analogues with a nitrogen content of up to 17.72 wt% that are prepared by the pyrolysis of a nitrogen-containing zeolitic imidazolate framework at 800 degrees C under a nitrogen atmosphere. As an anode material for lithium-ion batteries, these particles retain a capacity of 2,132 mA hg(-1) after 50 cycles at a current density of 100 mA g(-1), and 785 mAh g(-1) after 1,000 cycles at 5 A g(-1). The remarkable performance results from the graphene analogous particles doped with nitrogen within the hexagonal lattice and edges.
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