Journal
NATURE COMMUNICATIONS
Volume 2, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/ncomms1210
Keywords
-
Categories
Funding
- KAKENHI [22241026]
- NICT (National Institute of Information and Communication Technology), Japan
- Spanish MICINN [FIS2009-12721-C04-01]
- Grants-in-Aid for Scientific Research [22241026] Funding Source: KAKEN
Ask authors/readers for more resources
In molecular spintronics, the spin state of a molecule may be switched on and off by changing the molecular structure. Here, we switch on and off the molecular spin of a double-decker bis(phthalocyaninato) terbium(III) complex (TbPc(2)) adsorbed on an Au(111) surface by applying an electric current via a scanning tunnelling microscope. The dI/dV curve of the tunnelling current recorded onto a TbPc(2) molecule shows a Kondo peak, the origin of which is an unpaired spin of a pi-orbital of a phthalocyaninato (Pc) ligand. By applying controlled current pulses, we could rotate the upper Pc ligand in TbPc(2), leading to the disappearance and reappearance of the Kondo resonance. The rotation shifts the molecular frontier-orbital energies, quenching the pi-electron spin. Reversible switching between two stable ligand orientations by applying a current pulse should make it possible to code information at the single-molecule level.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available