4.6 Article

Highly sensitive explosive sensing by aggregation induced phosphorescence'' active cyclometalated iridium(III) complexes

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 3, Issue 21, Pages 5450-5456

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc00963d

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Funding

  1. Department of Science and Technology (DST), Govt. of India [SR/S1/IC-48/2009, SB/S1/IC-13/2014]
  2. Council of Scientific and Industrial Research (CSIR) [01/2551/12/EMR-II]

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Two phosphorescent complexes [Ir(o-CHOppy)(PPh3)(2)(H)Cl] (1) and [Ir(ppy)(PPh3)(2)(H)Cl] (2) exhibiting 'aggregation induced phosphorescent emission (AIPE)' properties have been found to be very sensitive to the detection of picric acid (PA). The detection limit for PA has been checked and was found to be 264 nM and 65 nM for complexes 1 and 2, respectively.

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