4.6 Article

An ABA triblock copolymer strategy for intrinsically stretchable semiconductors

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 3, Issue 15, Pages 3599-3606

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4tc02476a

Keywords

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Funding

  1. National Basic Research Program of China [2012CB723406]
  2. National Natural Science Foundation of China [61107014, 51203039, 21204017, 21174036, 51103034]
  3. Program for New Century Excellent Talents in University [NCET-12-0839]

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A novel semiconductor-rubber-semiconductor (P3HT-PMA-P3HT) triblock copolymer has been designed and prepared according to the principle of thermoplastic elastomers. It behaves as a thermoplastic elastomer with a Young's modulus (E) of 6 MPa for an elongation at break of 140% and exhibits good electrical properties with a carrier mobility of 9 x 10(-4) cm(2) V-1 s(-1). This novel semiconductor may play an important role in low-cost and large-area stretchable electronics.

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