Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 3, Issue 12, Pages 2940-2952Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc00009b
Keywords
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Funding
- Science and Engineering Board (SERB), DST, Govt. of India [SB/S1/PC-37/2012]
- Board of Research in Nuclear Sciences-Department of Atomic Energy (BRNS-DAE) [2012/34/31/BRNS/1039]
- Ministry of Human Resource Development for Centre of Excellence in FAST [5-7/2014-TS-VII]
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A new class of blue light emitting liquid crystalline star-shaped molecules based on 1,3,4-thiadiazoles have been designed and synthesized. These compounds were investigated using polarizing optical microscopy, differential scanning calorimetry, X-ray diffraction, cyclic voltammetry and photophysical studies. In comparison to their 1,3,4-oxadiazole counterparts, these thiadiazole-based molecules are promising as they stabilize the hexagonal columnar phases over a broad thermal range. The thermal behavior and photophysical properties of these new star-shaped molecules are extremely dependent on the number and types of peripheral tails in the molecular structure. 1,3,4-Thiadiazole derivatives exhibit sky-blue emission in solution, unlike the deep blue emission of 1,3,4-oxadiazole derivatives. They also exhibit a lower band gap as compared to their oxadiazole counterparts and offer great potential in organic light emitting diode applications.
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