Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 3, Issue 40, Pages 10381-10387Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc01434d
Keywords
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Funding
- National Basic Research Program of China [2013CB632502]
- National Natural Science Foundation of China [51172174, 51402222]
- 111 Project of China [B07040]
- Fundamental Research Funds for the Central Universities [WUT: 2013-YB-013]
- CERC-CVC joint U.S.-China Program - U.S. Department of Energy [DE-PI0000012]
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Sb-doped Mg2Si0.3Sn0.7 solid solutions were prepared by a two-step solid state reaction method followed by electron-discharge plasma activated sintering (Ed-PAS). Thermal stability was tested by changing heat treatment conditions, i.e., annealing temperature, annealing time, annealing atmosphere and preventive coatings. Mg loss is severe when the solid solutions are annealed in vacuum, due to the high saturated vapor pressure of Mg. As a consequence of Mg loss, the beta Sn-Sb alloy formed. However, the solid solutions are oxidized when annealed in air. And this is effectively prevented when the samples are coated with boron nitride (BN) spray. The results showed that Mg2Si1-xSnx can be exposed for long periods of time to temperature up to about 823 K, provided it is protected with specific coatings. However, the structure becomes unstable when the temperature exceeds much beyond 823 K, mainly due to the peritectic reaction. The composition, microstructure and thermoelectric (TE) properties of the annealed samples were carefully explored and critically assessed.
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