Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 3, Issue 31, Pages 8166-8182Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc01437a
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Funding
- Science and Engineering Board (SERB), DST, Govt. of India [SB/S1/PC-37/2012]
- Board of Research in Nuclear Sciences-Department of Atomic Energy (BRNS-DAE) [2012/34/31/BRNS/1039]
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A new class of polycatenars, where the central benzene ring is connected to two arms derived from substituted 1,3,4-thiadiazoles at the 1,3- and 1,4-positions, was synthesized and characterized. These thiadiazole-based molecules are promising as they stabilize columnar phases over a wide temperature range, in comparison to their oxadiazole analogues. The para-substituted polycatenars exhibited a columnar hexagonal and/or a columnar oblique phase, while the meta-substituted polycatenars exhibited solely a columnar oblique phase. The para-substituted polycatenars exhibited green emission, while the meta-substituted polycatenars exhibited blue emission in solution and film states. Stabilization of a broad range columnar phase and luminescence in the solid state make these new compounds promising from the viewpoint of applications in emissive displays. The self-assembly and luminescence of these regioisomers was greatly influenced by the molecular structure.
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