4.6 Article

Symmetric naphthalenediimidequaterthiophenes for electropolymerized electrochromic thin films

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 3, Issue 23, Pages 5985-5994

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc00746a

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Funding

  1. Italian MiUR through FIRB - Futuro in Ricerca [RBFR08DUX6]
  2. PON RC (TESEO'') [PON02_00153-2939517]
  3. PON R&C (Plastic electronics for smart disposable systems'') [PON02_00355-3416798]
  4. KAU

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A new symmetric naphthalenediimidequaterthiophene (s-NDI2ODT4) was synthesized and exhibited the capability to electropolymerize alone or with EDOT affording polymers with controlled donor/acceptor monomer ratios. s-NDI2ODT4-EDOT-based copolymers showed low band gaps, wide optical absorption ranges extending to the near IR region, tuned electrical properties, thin-film surface morphology and hydrophilicity as well as high coloration efficiency in electrochromic devices.

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