Journal
JOURNAL OF CHEMICAL RESEARCH
Volume -, Issue 6, Pages 370-373Publisher
SCIENCE REVIEWS 2000 LTD
DOI: 10.3184/030823409X460939
Keywords
2-methyltetrahydrofuran; Grignard reactions; carbonyl compounds; alcohol synthesis
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Funding
- National Key Technology RD Program [2007BAI34B01]
- National Natural Science Foundation of China [20676123]
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Compared with tetrahydrofuran (THF) as a solvent for the addition reactions between Grignard reagents and carbonyl compounds 2-methyltetrahydrofuran affords the corresponding adducts in higher yields with higher chemoselectivities. Moreover, 2-methyltetrahydrofuran can be readily recycled and reused, which lowers the cost of the process and makes the reaction greener.
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