Journal
JOURNAL OF CHEMICAL RESEARCH
Volume -, Issue 8, Pages 479-483Publisher
SAGE PUBLICATIONS LTD
DOI: 10.3184/030823408X338701
Keywords
cyclophanes; McMurry reaction; [2.n]metacyclophane-1,2-diol; conformation; oxidation; 1,2-diketones
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McMurry cyclisation of 1,n-bis(5-formyl-2-methoxyphenyl)alkanes afforded dimethoxy[2.n]metacyclophan-1-enes and dimethoxy[2.n]metacyclophane-1,2-diols, in which latter one was converted to dimethoxy[2.n]metacyclophane-1,2-diones by Albright-Goldman oxidation.
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