Journal
CHEMICAL SCIENCE
Volume 5, Issue 7, Pages 2754-2760Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc53107d
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Funding
- Platform for Drug Discovery, Informatics, and Structural Life Science from the Ministry of Education, Culture, Sports, Science and Technology, Japan
- MEXT (Ministry of Education, Culture, Sports, Science and Technology) [24105513, 2304]
- JST (ACT-C)
- Grants-in-Aid for Scientific Research [13J06908] Funding Source: KAKEN
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We have developed the iodoarene-catalyzed nucleophilic fluorination of b-dicarbonyl compounds and intramolecular aminofluorination of u-amino-alkenes using the same reaction conditions. The key for this reaction is the in situ generation of a hypervalent iodine compound ArIF2 by hydrogen fluoride, mCPBA and a catalytic amount of iodoarene. Preliminary trials of catalytic asymmetric nucleophilic fluorination were conducted.
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