Journal
CHEMICAL SCIENCE
Volume 5, Issue 5, Pages 1956-1960Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc00255e
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Funding
- Princeton University
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The bis(phosphino)pyridine (PNP) cobalt(I) methyl complex, ((PNP)-P-iPr) CoCH3 is a rich platform for the oxidative addition of non-polar reagents such as H-2, the C-H bonds of arenes and terminal alkynes. Rare e-amples of he-acoordinate cobalt(III) compounds including a trihydride, a bis(acetylide) hydride and a trimethyl comple- have been isolated and two e-amples structurally characterized. These findings demonstrate that when placed in an appropriately strong ligand field, two- electron o-idative addition chemistry is possible with first row transition metals.
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