Journal
CHEMICAL SCIENCE
Volume 5, Issue 1, Pages 136-140Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc52449c
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Ministry of Education, Science, Sports and Culture, Japan [24655095]
- Grants-in-Aid for Scientific Research [11J09721] Funding Source: KAKEN
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Chiral monomers 1 and 2, carrying C-4(-) and C(3)(-)symmetric bowl-shape peptidic macrocycle cores, respectively, undergo supramolecular polymerization in solution via van der Waals and hydrogen bonding interactions. Size-exclusion chromatographic studies, using UV and CD detectors, on the supramolecular copolymerization of their enantiomers demonstrated that these monomers are the first chiral macrocycles that polymerize enantioselectively with a strong preference for chiral self-sorting.
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