4.8 Article

Selective formation of biphasic thin films of metal-organic frameworks by potential-controlled cathodic electrodeposition

Journal

CHEMICAL SCIENCE
Volume 5, Issue 1, Pages 107-111

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc51815a

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Funding

  1. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0006937]
  2. MIT's Research Support Committee for Non-Tenured Faculty Funds
  3. MISTI Hayashi Fund
  4. MRSEC Shared Experimental Facilities at MIT
  5. NSF [DMR-0819762, CHE-9808061, DBI-9729592]

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Cathodic electrodeposition lends itself to the formation of biphasic metal-organic framework thin films at room temperature from single deposition baths using potential bias as the main user input. Depending on the applied potential, we selectively deposit two different phases as either bulk mixtures or bilayer films.

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