4.8 Article

Copper catalyzed direct alkenylation of simple alkanes with styrenes

Journal

CHEMICAL SCIENCE
Volume 5, Issue 6, Pages 2379-2382

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc00093e

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Funding

  1. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)

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A novel Cu-catalyzed direct alkenylation of simple alkanes with styrenes was described. In the presence of a catalytic amount of Cu(OTf)(2), a diverse range of alkenes undergo coupling with cycloalkanes to produce (E)-alkyl alkenes. This transformation is proposed to proceed via a radical process.

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