Journal
CHEMICAL SCIENCE
Volume 5, Issue 2, Pages 462-470Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc52538d
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Funding
- National Institute of General Medical Sciences, National Institutes of Health
- National Science Foundation
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM036700] Funding Source: NIH RePORTER
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Torsional effects control the pi-facial stereoselectivities of a variety of synthetically important organic reactions. This review surveys theoretical calculations that have led to the understanding of the influence of the torsional effects on several types of stereoselective organic reactions, especially electrophilic additions and cycloadditions to alkenes.
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