4.8 Article

Aggregation-induced emission enhancement of a meso-trifluoromethyl BODIPY via J-aggregation

Journal

CHEMICAL SCIENCE
Volume 5, Issue 2, Pages 751-755

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc52495g

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Funding

  1. National Research Foundation
  2. Korean government [NRF-2012R1A1A2038694]
  3. National Research Foundation of Korea [2012R1A1A2038694] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A CF3-BODIPY forms strongly luminescent aggregates, which contrasts with the quenched condensed-phase photophysics that are typical for BODIPY dyes. Examination of the luminescent properties of these aggregates - narrow red-shifted absorption and emission bands, minimal Stokes shift and increased fluorescence rate constants - and of the solid-state packing of the dye establish the CF3-BODIPY as the first structurally characterized genuine BODIPY J-aggregate.

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