Journal
CHEMICAL SCIENCE
Volume 5, Issue 4, Pages 1354-1360Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc53250j
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Funding
- National Institutes of Health [GM33049]
- National Science Foundation [CHE-0948222]
- Abbott Laboratories Stanford Graduate Fellowship
- NIH [GM083428]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1145236] Funding Source: National Science Foundation
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The palladium-catalyzed oxidative desymmetrization of meso-dibenzoates yields g-benzoyloxy cycloalkenones in good yields and with excellent levels of enantioselectivity. These compounds serve as precursors to a broad range of substituted cycloalkenones, including well-established synthetic building blocks and elaborated cycloalkanone derivatives. The ability to prepare both enantiomers of the oxidative desymmetrization products enables a unified strategy toward stereochemically diverse epoxyquinoid natural products.
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