Journal
CHEMICAL SCIENCE
Volume 4, Issue 3, Pages 886-896Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc21524a
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Funding
- DFG
- Fonds der Chemischen Industrie
- AstraZeneca
- Ministry for Science and Culture of Lower Saxony
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Significant progress has been accomplished in direct olefinations through twofold C-H bond functionalization of arenes and heteroarenes employing readily accessible, selective and relatively inexpensive ruthenium catalysts. Particularly, ruthenium(II) complexes have allowed challenging direct double C-H/C-H bond alkenylations of arenes with ample scope. These catalysts set the stage for step-economical C-H/C-H bond functionalization with electron-rich as well as electron-deficient arenes and heteroarenes, and, thereby, provide versatile access to diversely decorated styrenes.
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