Journal
CHEMICAL SCIENCE
Volume 4, Issue 11, Pages 4187-4192Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc51993g
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Funding
- National Science Foundation of China [21002087, 21142002, 21272206, J1210042]
- Fundamental Research Funds for the Central Universities [2010QNA3033]
- Zhejiang Provincial NSFC [Z12B02000]
- Qianjiang Project [2013R10033]
- Specialized Research Fund for the Doctoral Program of Higher Education [20110101110005]
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The Pd(II)-catalyzed alkoxylation of unactivated C(sp(3))-H and C(sp(2))-H bonds using a new bidentate directing group has been developed. Alkoxylation occurs selectively at the beta position with broad substrate scope and high tolerance of functional groups (chloro, cyano, ether, ester, olefin, amino, etc.). Besides alkoxylation of the beta-C-H bonds, gamma-alkoxylation of C(sp(2))-H bonds could also be achieved, provided that no reactive beta-C-H bonds were present. In addition, this DG is readily available and removable.
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