4.8 Article

Number of outer electrons as descriptor for adsorption processes on transition metals and their oxides

Journal

CHEMICAL SCIENCE
Volume 4, Issue 3, Pages 1245-1249

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc21601a

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Funding

  1. Direct For Mathematical & Physical Scien [0843934] Funding Source: National Science Foundation
  2. Division Of Materials Research [0843934] Funding Source: National Science Foundation

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The trends in adsorption energies of the intermediates of the oxygen reduction and evolution reactions on transition metals and their oxides are smoothly captured by the number of outer electrons. This unique descriptor permits the construction of predictive adsorption-energy grids and explains the existence of scaling relationships among these compounds.

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