Journal
CHEMICAL SCIENCE
Volume 4, Issue 6, Pages 2675-2679Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50577d
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Funding
- NSF of China [21102133, 21172200]
- NSF of Henan [082300423201]
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A novel strategy of dehydrogenative Heck reaction controlled by redox process of ferrocene has been developed. Commercially available chiral amino acid as ligand realized asymmetric dehydrogenative Heck reaction, leading to planar-chiral ferrocene derivatives with excellent enantioselectivity and in good to excellent yields (up to 99% ee and 98% yield).
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