Journal
CHEMICAL SCIENCE
Volume 4, Issue 6, Pages 2447-2452Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50245g
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Funding
- Ministry of Science and Technology [2009CB623601, 2013CB933501]
- National Natural Science Foundation of China
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For the first time, ambient-stable and balanced carrier transport is achieved in polymer ambipolar field-effect transistors (FETs) and inverters with high performance. With chlorinated isoindigo polymers, FETs fabricated in ambient conditions show hole mobilities up to 0.81 cm(2) V-1 s(-1) and dramatically increased electron mobilities from 10(-2) to 0.66 cm(2) V(-)1 s(-1). Hence, chlorination is effective to modulate electronic properties and improve the device performance of conjugated polymers.
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