4.8 Article

Stereoselective intramolecular cyclopropanation through catalytic olefin activation

Journal

CHEMICAL SCIENCE
Volume 4, Issue 3, Pages 1105-1110

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc21914j

Keywords

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Funding

  1. Max-Planck Society
  2. Max-Planck-Institut fur Kohlenforschung
  3. Deutsche Forschungsgemeinschaft [MA-4861/4-1]
  4. Fundacao para a Ciencia e Tecnologia [PEst-OE/QUI/UI0100/2011, PTDC/QUI-QUI/099389/2008]
  5. Fundação para a Ciência e a Tecnologia [PTDC/QUI-QUI/099389/2008] Funding Source: FCT

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A novel stereoselective and convergent catalytic method for the cyclopropanation of electron-neutral and -rich olefins by sulfonium ylides is reported which unusually proceeds through olefin activation rather than by metal carbene formation.

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