Journal
CHEMICAL SCIENCE
Volume 4, Issue 6, Pages 2690-2694Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50810b
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Funding
- Natural Science Foundation of China [21172060]
- Fundamental Research Funds for the Central Universities (Hunan University) [2011-015]
- Hunan Provincial Natural Science Foundation of China [13JJ2018]
- China Postdoctoral Science Foundation [2012M511716]
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A metal-free oxidative tandem coupling of activated alkenes with carbonyl C(sp(2))-H bonds and aryl C(sp(2))-H bonds using TBHP is established for the synthesis of 3-(2-oxoethyl)indolin-2-ones. This method allows 1,2-difunctionalization of the C-C double bond in N-arylacrylamides by simultaneous formation of two C(sp(2))-C(sp(3)) bonds.
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