Journal
CHEMICAL SCIENCE
Volume 4, Issue 4, Pages 1658-1662Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50155h
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Funding
- Swiss National Science Foundation
- EPFL
- Marie Curie Initial Training Network DYNAMOL
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Boronic acid-capped clathrochelates were used to build rigid, linear bipyridyl ligands with adjustable lengths between 1.5 and 5.4 nm. The syntheses can be accomplished in one or two steps from simple starting materials. The potential of these ligands as building blocks for metallasupramolecular chemistry is unveiled through the preparation of a discrete metallamacrocyclic structure and a heterometallic coordination polymer.
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