Journal
CHEMICAL SCIENCE
Volume 4, Issue 6, Pages 2418-2422Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50725d
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Funding
- DFG
- International Research Training Group Catalysts and Catalytic Reactions for Organic Synthesis [IRTG 1038]
- Krupp Foundation
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Hydroformylation of alkynes is an underdeveloped atom-economic and redox-neutral method to prepare enals. Applying a new electron poor self-assembling ligand system provides the first general rhodium-catalyst for the chemo- and stereoselective hydroformylation of dialkyl- as well as diaryl-substituted alkynes to furnish enals in excellent chemo- and stereoselectivity.
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