Journal
CHEMICAL SCIENCE
Volume 4, Issue 5, Pages 2248-2252Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc22130j
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Funding
- JSPS
- MEXT (Japan)
- Grants-in-Aid for Scientific Research [25870335, 21000006, 24106716] Funding Source: KAKEN
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An efficient approach for the design of chiral quaternary phosphonium bromides as chiral phase-transfer catalysts was demonstrated. A catalyst library of phosphonium salts with various structures was readily constructed using commercially available chiral phosphines as catalyst precursors, and an optimized catalyst was successfully applied to highly enantioselective conjugate additions under base-free phase-transfer conditions with low catalyst loading.
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