Journal
CHEMICAL SCIENCE
Volume 4, Issue 4, Pages 1484-1489Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc21995j
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Funding
- 973 Program [2011CBA00507, 2011CB932504]
- National Nature Science Foundation of China [21131006]
- Knowledge Innovation Program of the Chinese Academy of Sciences [KJCX2-EW-H01]
- NSF of Fujian Province
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Two classical metal clusters, (Cu4I4)-I-I and (Cu6S6)-S-I, are introduced as functional connecting nodes to construct a novel multi-metal-cluster MOF [((Cu4I4)-I-I)(3)(Cu-6(I))(2)(3-ptt)(12)](n)center dot 24nDEF center dot 12nH(2)O (1) that incorporate their inherent luminescent properties, induced by their respective metal-metal interactions. These two distinct clusters are combined together for the first time to perform as functional luminophores that display unusual dual emission with both thermochromic luminescence and near-infrared (NIR) character.
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