Journal
CHEMICAL SCIENCE
Volume 3, Issue 6, Pages 2153-2157Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc01007k
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Funding
- Leverhulme Trust [F/00 203/T]
- Royal Society
- EPSRC [EP/H000925/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
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Rigid organic iminospherand cages are rendered meltable by multiple alkylation; below their melting points they can take the form of permanently porous crystals, crystals unstable to desolvation or nonporous glassy solids depending on chain length and branching; melting points as low as 50 degrees C are observed and a fully Newtonian liquid phase is obtained above 80 degrees C. Thin glassy fibres can be drawn out from a molten phase.
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