4.8 Article

Heterometallic Cu-II/Dy-III 1D chiral polymers: chirogenesis and exchange coupling of toroidal moments in trinuclear Dy-3 single molecule magnets

Journal

CHEMICAL SCIENCE
Volume 3, Issue 4, Pages 1169-1176

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc00728b

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Funding

  1. EU
  2. AvH Foundation
  3. INPAC
  4. Methusalem from K. U. Leuven
  5. DFG Center for Functional Nanostructures

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The first example of exchange coupling between the toroidal moments in chiral heterometallic Cu-II/Dy-III 1D polymers built from alternating trinuclear Dy-3 SMM-building blocks and chiral copper( II) complexes is reported. A very strong toroidal magnetization can be induced by applying a magnetic field at low temperature in single-crystals of these compounds.

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