4.8 Article

A single-molecule magnet assembly exhibiting a dielectric transition at 470 K

Journal

CHEMICAL SCIENCE
Volume 3, Issue 12, Pages 3366-3370

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc21023a

Keywords

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Funding

  1. MOST (973 program) [2012CB821702]
  2. NSFC [90922032, 21171100]
  3. 111 Project [B12015]
  4. MOE Innovation Team [IRT0927]
  5. DFG Center for Functional Nanostructures
  6. ERC Advanced Grant [226558]
  7. KU Leuven

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A triangular Dy(III) single-molecule magnet (SMM) exhibiting ferroelectric bistability is assembled in an acentric space group Pna2(1). Hysteresis loops associated with its SMM behavior together with a two-step slow relaxation of the magnetization are observed below 30 K. A transition with dielectric anomalies between a paraelectric and a ferroelectric phase occurs at 470 K.

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