Journal
CHEMICAL SCIENCE
Volume 3, Issue 9, Pages 2843-2848Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc20448g
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Funding
- CEA nuclear energy division CEA/DEN/DSOE
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In addition to Lewis' octets and Langmuir's 18-electron principle, 32-electron centered systems are possible. We now propose a new, third example on 32e-bonding between a central metal atom and a ligand cage. Moreover, these actinide-filled Si-20 clusters could lead to novel silicon nanostructures.
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