Journal
CHEMICAL SCIENCE
Volume 3, Issue 6, Pages 1825-1828Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc20238g
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Funding
- ETH [ETH-11 10-3]
- David Lucile & Packard Foundation
- Ono Corporation
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A shapeshifting organic molecule dynamically adjusts its equilibrium population of discrete structural isomers in response to an analyte. By incorporating a single C-13-label into the bullvalene core, these changes can be read by a single C-13 NMR experiment. The shapeshifting nature and C-13 nucleus together act as a reporting element that generates a reproducible pattern from small changes in the chemical shifts and intensities of the carbon peaks.
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