4.8 Article

A dissymmetric molecular capsule with polar interior and two mechanically locked hemispheres

Journal

CHEMICAL SCIENCE
Volume 3, Issue 1, Pages 186-191

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00668a

Keywords

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Funding

  1. MICINN [CTQ2008-00222/BQU, CSD2006-0003]
  2. DURSI [2009SGR6868]
  3. ICIQ Foundation
  4. ICREA Funding Source: Custom

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The synthesis and chiral resolution of a dissymmetric tetraurea-calix[4]pyrrole/tetraurea- calix[4]arene molecular capsule with two hemispheres mechanically locked is described. The assembly features a bis-[2]catenated topology and shows reversible molecular co-encapsulation of two different neutral molecules or two oppositely charged ions.

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