Journal
CHEMICAL SCIENCE
Volume 3, Issue 2, Pages 466-469Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sc00693b
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Funding
- Japan Society for the Promotion of Science (JSPS) [2692]
- Global COE of the Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [20225006, 10J02692] Funding Source: KAKEN
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The peptide-linked bisbipyridine separated by a rigid or flexible spacer formed a dinuclear FeII complex, which showed a unique solvent-induced inversion and on-off switching of the metal-centered chirality depending on the spacer, resulting from the supramolecular structural change between a dinuclear helicate and a mono peptide ligand-bridged dinuclear Fe-II complex. The rigid and flexible spacer groups connecting the peptide residues are responsible for these unique structural and chiroptical properties occurring at the metal center.
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